The chat show, hosted by Jayne Azzopardi, will give fans behind-the-scenes gossip and never-before-seen clips from the season.
Azzopardi will also be joined by Shelly Horton and former MAFS bride Cheryl Maitland.
In 2017 Maitland was firstly matched with groom Jonathan Troughton, but after their 'marriage' ended, she requested to be matched with Andrew Jones.
Although both those relationships from the show weren't successful, the model has gone on to find love with boyfriend Dean Gibbs.
Talking Married will air every Thursday on 9Life.